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Barcelona — Villarreal
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Kick-off on September 24, 2019, at 10:00 p.m.
Barcelona repeated the result of the match with Real Betis, having defeated Valencia with a score of 5-2 at the Camp Nou. The Catalans are already starting in the Champions League group stage this week, so the team's game schedule will become much harder. Villarreal have little chance of a positive result, but nobody will give up.