Kick-off: November 4, 2025, at 22:00.

In the fourth round of the UEFA Champions League group stage, Olympiakos will host Dutch side PSV at the Georgios Karaiskakis Stadium in Piraeus. The teams have faced each other three times, most recently in the 2021-22 Europa League. Back then, the Greek club won 4-2 at home and lost 1-2 in Eindhoven. Olympiakos advanced on aggregate.

Watch Olympiakos – PSV on November 4, 2025, online at MEGOGO.

Olimpiakos has earned one point so far in this Champions League campaign, after a draw with Cyprus’ Pafos in the first round. The team then lost to Arsenal and Barcelona, with the match against the Catalans ending in a 1-6 defeat. After that loss, José Luis Mendilibar’s squad stabilized their domestic form, recording three consecutive wins while conceding only one goal.

PSV, after losing to Union Saint-Gilloise in the second round, drew with Bayer Leverkusen and then sensationally thrashed Napoli 6-2. Peter Bosz’s team is in excellent form, with an unbeaten streak across all competitions reaching eight matches. In the last five games, the Reds and Whites scored 20 goals, showing outstanding attacking efficiency.

Watch the broadcast of Olympiakos – PSV on November 4, 2025, online at MEGOGO.