Kick-off: October 21, 2025, at 22:00.

In the third round of the UEFA Champions League group stage, PSV will host Napoli at Philips Stadion in Eindhoven. The Dutch team has one point, while the Italian team has three. These clubs have met before — in the 2012–13 Europa League. Back then, PSV secured a confident 3-0 home win. Jeremain Lens opened the scoring, and Belgian Dries Mertens added the second goal; a few months later, Mertens joined Napoli and became one of the club’s legends.

Watch PSV – Napoli live online on MEGOGO on October 21, 2025. PSV lost 1-3 to Royal Union Saint-Gilloise in the opening round, scoring a consolation goal in the 90th minute. In the second round, Marcel van Bommel’s team drew 1-1 at Bayer Leverkusen, despite having early Ivan Perišić goal disallowed for offside. In PSV’s last fifteen home Champions League matches, the team kept a clean sheet only twice — against Lens (1-0) and Girona (4-0). During this period, PSV conceded 24 goals, highlighting defensive instability.

Napoli lost 0-2 to Manchester City at the Etihad in the opening round, going down to ten men as early as the 21st minute. Then, at the Stadio Diego Armando Maradona, the Italian team defeated Sporting 2-1, thanks to a brace from Rasmus Højlund and two assists from Kevin De Bruyne. Napoli previously played in the Netherlands: losing 1-2 to Feyenoord in 2017 but defeating Ajax 6-1 in 2022. In five of their last ten Champions League away matches, Napoli scored at least two goals and remains one of the most prolific teams in the tournament. Watch the live broadcast of PSV – Napoli on MEGOGO on October 21, 2025.