Kick-off on November 26, 2025, at 22:00.

In Matchday 5 of the main stage of the UEFA Champions League, Liverpool and PSV will face off at Anfield. The hosts sit eighth in the table with nine points, while the visitors are eighteenth with five. The sides have met three times in England within the competition, all in the late 2000s. In Group C of the 2006/07 campaign, two assists from Dirk Kuyt helped Liverpool claim all three points, 2–0. Later that same season, the teams met again in the quarterfinals, where the Merseysiders secured a win while playing with a man advantage, 1–0. In Group D of the 2008/09 UCL season, the Reds once more proved stronger at home, 3–1.

At Anfield in the main stage, Liverpool defeated two clubs from Madrid: Atlético, 3–2, and Real Madrid, 1–0. Hungarian midfielder Dominik Szoboszlai has been involved in four of the team’s nine scoring plays in this phase. The club has won ten of its previous twelve home matches in the competition. The last time the Merseysiders dropped points at home in the Champions League in the autumn was in 2020, when they hosted Atalanta and lost 2–0. Aside from their upcoming opponent, the Reds have hosted other Dutch teams in the competition: Ajax, 2–2 in the 1966/67 season, and AZ Alkmaar, 3–2 in the 1981/82 campaign.

Watch Liverpool vs. PSV on November 26, 2025, live on MEGOGO. PSV drew 1–1 away against Olympiacos and Bayer Leverkusen. American forward Ricardo Pepi has scored twice and provided an assist in this phase. The Lightbulbs have earned only three victories in their last seventeen Champions League road matches. Over that span, the side has recorded nine draws away from home. In the 21st century, the Farmers have also traveled in the tournament to face Manchester United, Tottenham, and Arsenal. Watch the Liverpool vs. PSV broadcast on November 26, 2025, online on MEGOGO.